Total waterborne carbon export and DOC composition from ten nested subarctic peatland catchments—importance of peatland cover,groundwater influence,and inter‐annual variability of precipitation patterns

Waterborne carbon (C) export from terrestrial ecosystems is a potentially important flux for the net catchment C balance and links the biogeochemical C cycling of terrestrial ecosystems to their downstream aquatic ecosystems. We have monitored hydrology and stream chemistry over 3 years in ten nested catchments (0.6–15.1 km²) with variable peatland cover (0%–22%) and groundwater influence in subarctic Sweden. Total waterborne C export, including dissolved and particulate organic carbon (DOC and POC) and dissolved inorganic carbon (DIC), ranged between 2.8 and 7.3 g m^–2 year^–1, representing ~10%–30% of catchment net ecosystem exchange of CO₂. Several characteristics of catchment waterborne C export were affected by interacting effects of peatland cover and groundwater influence, including magnitude and timing, partitioning into DOC, POC, and DIC and chemical composition of the exported DOC. Waterborne C export was greater during the wetter years, equivalent to an average change in export of ~2 g m^–2 year^–1 per 100 mm of precipitation. Wetter years led to a greater relative increase in DIC export than DOC export due to an inferred relative shift in dominance from shallow organic flow pathways to groundwater sources. Indices of DOC composition (SUVA₂₅₄ and a₂₅₀/a₃₆₅) indicated that DOC aromaticity and average molecular weight increased with catchment peatland cover and decreased with increased groundwater influence. Our results provide examples on how waterborne C export and DOC composition might be affected by climate change. Copyright © 2012 John Wiley & Sons, Ltd.     

Controls on the morphology of braided rivers and braid bars: An empirical characterization of numerical models

Braided rivers exhibit highly variable morphologies, morphodynamic behaviours and resulting depositional records. To evaluate relationships between characteristics of braided-river channel belts and river depth, water discharge and streambed gradient, 39 numerical modelling experiments were conducted with the software Delft3D to simulate braided-river evolution under a broad range of boundary conditions. Data from model outputs were integrated with observations from 63 natural braided rivers differing with respect to river depth and streambed gradient. The modelled rivers each underwent similar evolutions, yet each culminated in markedly different final river morphologies, dependent on discharge and riverbed gradient. The rivers underwent evolutionary stages of: (i) formation of transverse unit bars with limited relief from an initially featureless bed; (ii) channel development around bars and in some cases dissecting transverse unit bars; (iii) formation of relatively simpler compound bars; and (iv) amalgamation of these simpler compound bars into more complex compound bars. Quantitative relationships relating to braided-river channel-belt morphology and organization are established, and the following results are noted: (i) bar elongation (length-to-width ratio) is correlated positively with riverbed gradient; (ii) bar height and area are correlated positively with discharge, and negatively with riverbed gradient; (iii) the river depth is the main predictor of mean braid-bar area; and (iv) the degree of braiding is primarily associated with river width-to-depth ratio and riverbed gradient. Results arising from this research improve our understanding of controls on the morphology and architectures of braided fluvial channel belts; they provide a novel empirical characterization that can be applied for predicting channel depth, bar morphology, streambed gradient, and degree of braiding of modern fluvial systems and of the formative rivers of ancient preserved successions.     

Post-Marquette discharge from Glacial Lake Agassiz into the Superior basin

Glacial Lake Agassiz, the largest of the North American glacial lakes, discharged through several different outlets during its history, although the timing and location of discharge remain controversial. However, one discharge event is well established based on extensive onshore observations: drainage through the Nipigon Lake area into the Superior basin about 10,700 years ago, following retreat of ice of the Marquette advance from the basin. High-resolution, single-channel seismic-reflection data collected with a small airgun were acquired to test the hypothesis that the Post-Marquette drainage event left diagnostic stratigraphic and geomorphic signatures beneath Lake Superior. The unique bathymetry of northwestern Lake Superior, where water depth plunges off Nipigon and Black Bays, makes this location ideal for the characterization of the post-Marquette depositional and erosional features. According to our hypothesis, the initial, sudden discharge of high-velocity water would have eroded channels through the bays. The steep and sudden drop-off into the Superior basin would have caused the flow to slow and drop much of the sediment it was carrying. Our results confirm the existence of both erosional features and depositional sediment packages related to Lake Agassiz discharge at this time. The erosional features include deeply incised bedrock channels in the bays. The depositional features comprise subaqueous fans that are thickest in the deep water areas adjacent to the outlets and thin lakeward and laterally away from the channels. The seismic character of the basal units of the fans, proximal to the channels, is chaotic and only very weakly stratified, suggesting that these deposits represent coarse sediment laid down during the initial, high-energy stages of the flood. These sediments are overlain by a stratified package which is interpreted as the fine grained sediment associated with the later, low-energy stages of the flood. The combination of channels and subaqueous fans is inferred to be diagnostic of high-energy Lake Agassiz discharge into the Superior basin, and they serve as analogs for hypothesized discharge at other times.     

Patterns of development in tourist accommodation enterprises on farms in England and Wales

The spatial distribution of UK farm-based tourist accommodation is not known in detail, although this type of facility has been an important element in the growth of rural tourism and the most common option for farm diversification. A database of farms in England and Wales offering tourist accommodation has been prepared and the individual entries georeferenced to enable their locations to be determined with respect to selected Scenic Areas (Areas of Outstanding Natural Beauty, Heritage Coasts and National Parks). Exploratory analysis of this database indicates a possible ‘neighbourhood effect’ in which the provision of farm-based accommodation within buffer zones immediately surrounding these designated areas has a higher level of penetration in the farming community than in more distant areas. Further research is outlined to examine the interaction between actors in farming and planning communities using the geographical framework presented here.     

A simple method to reduce discharge of sewage microorganisms from an Antarctic research station

The majority of coastal Antarctic stations release untreated sewage into the near-shore marine environment. This study examined bacterial reproduction within the temporary sewage-holding tanks of Rothera Research Station (Adelaide Island, Antarctic Peninsula) and monitored sewage pollution in the local marine environment. By continuously flushing the sewage-holding tanks with cold seawater we inhibited microbial reproduction and decreased the numbers of bacteria subsequently released into the sea by >90%. The widespread use of this simple method could significantly reduce the numbers of faecal coliform and other non-native microorganisms introduced into the Antarctic marine environment.     

Magnetohydrodynamics of stellar interiors

David Hughes, Robert Rosner and Nigel Weiss describe what was achieved during a programme on stellar magnetic fields at the Isaac Newton Institute in Cambridge. Over a four-month period more than 90 participants visited the Institute for a mixture of structured workshops and informal collaboration.     

Relative contributions of silicate and carbonate rocks to riverine Sr fluxes in the headwaters of the Ganges

Exhumation of the Himalayan-Tibetan orogen is implicated in the marked rise in seawater ⁸⁷Sr/⁸⁶Sr ratios since 40 Ma. However both silicate and carbonate rocks in the Himalaya have elevated ⁸⁷Sr/⁸⁶Sr ratios and there is disagreement as to how much of the ⁸⁷Sr flux is derived from silicate weathering. Most previous studies have used element ratios from bedrock to constrain the proportions of silicate- and carbonate-derived Sr in river waters. Here we use arrays of water compositions sampled from the head waters of the Ganges in the Indian and Nepalese Himalaya to constrain the end-member element ratios. The compositions of tributaries draining catchments restricted to a limited range of geological units can be described by two-component mixing of silicate and carbonate-derived components and lie on a plane in multicomponent composition space. Key elemental ratios of the carbonate and silicate components are determined by the intersection of the tributary mixing plane with the planes Na = 0 for carbonate and constant Ca/Na for silicate. The fractions of Sr derived from silicate and carbonate sources are then calculated by mass-balance in Sr-Ca-Mg-Na composition space. Comparison of end-member compositions with bedrock implies that secondary calcite deposition may be important in some catchments and that dissolution of low-Mg trace calcite in silicate rocks may explain discrepancies in Sr-Ca-Na-Mg covariation. Alternatively, composition-dependent precipitation or incongruent dissolution reactions may rotate mixing trends on cation-ratio diagrams. However the calculations are not sensitive to transformations of the compositions by incongruent dissolution or precipitation processes provided that the transformed silicate and carbonate component vectors are constrained. Silicates are calculated to provide ∼50% of the dissolved Sr flux from the head waters of the Ganges assuming that discrepancies between Ca-Mg-Na covariation and the silicate rock compositions arise from addition of trace calcite. If the Ca-Mg-Na mixing plane is rotated by composition-dependent secondary calcite deposition, this estimate would be increased. Moreover, when ⁸⁷Sr/⁸⁶Sr ratios of the Sr inputs are considered, silicate Sr is responsible for 70 ± 16% (1σ) of the ⁸⁷Sr flux forcing changes in seawater Sr-isotopic composition. Since earlier studies predict that silicate weathering generates as little as 20% of the total Sr flux in Himalayan river systems, this study demonstrates that the significance of silicate weathering can be greatly underestimated if the processes that decouple the water cation ratios from those of the source rocks are not properly evaluated.     

Bentonites in the Chalk of central eastern England and their relation to the opening of the Northeast Atlantic

Within the post-Cenomanian Chalk sequence of central eastern England about 20 thin persistent marl horizons occur. These marls contain from 30 to 65% non-carbonate material the bulk of which is composed of a well crystallised Mg-rich smectite with a notable paucity of illite and quartz. The Chalk matrix above and below the marls contains up to 2.0% of non-carbonate matter which again is dominated by the presence of an Mg-rich smectite but which contains a larger proportion of illite and quartz than occurs in the marls. For both sets of non-carbonate materials the excellent crystallinity and Mg-rich nature of the smectite strongly suggest that it was formed by the in situ alteration of an aeolian transported volcanic ash, i.e. it is a true bentonite. Quartz and illite in the Chalk matrix are probably detrital components.Relative to a standard shale, non-carbonate materials from the Chalk marl horizons exhibit a highly anomalous trace element pattern with accentuated levels of Zr, Nb and Th but depleted levels of Ba, Rb and K. This trace element chemistry corroborates a volcanogenic origin for the smectite insofar as it is not explicable in terms of any realistic sedimentary process. The chemistry is best interpreted in terms of the magnetic processes responsible for the formation of the original ash precursor of the marls. It appears that this precursor had a pantelleritic composition and therefore originated from a source overlying an area where incipient continental rifting was taking place.Micromorphological examinations prove that residues from the Chalk marls contain small amounts of pyroclastic debris, including pumice and fragments of sideromelane glass. The morphology of the fragments suggests that the volcanic eruptions responsible for the ejection of the original ash into the air were of the shallow-water phreatomagmatic (Surtseyan) type.The distribution of marls in the Chalk of eastern England suggests that the ashfalls responsible for their origin were of the tropospheric type and were drawn by westerly winds from a centre to the west or northwest of mainland Britain. Of the numerous volcanic centres that lie in offshore areas to the west, the Anton Dohrn Seamount in the Rockall Trough appears to a likely centre of origin for the ashfalls. However, ashfalls responsible for the formation of the traces of smectite in the Chalk matrix were probably of the general background (stratospheric) type and may have been drawn from more distant centres.Volcanism at the Anton Dohrn Seamount was related to tensional effects in the continental crust that immediately preceded the formation of the Rockall Trough and the separation of Greenland from northwestern Europe during Tertiary times. Activity at the centre, and Cretaceous bentonites derived therefrom, therefore represent the earliest stages in the development of the Thulean igneous province.